ECDH is included in the ciphersuites, so the only answer is: yes, this should be possible.
For your further research, it might help to know that Crypto.SE features a lot of Q&As related to “OpenSSL ECDHOpenSSL ECDH”.
Also see the related documentation at the OpenSSL wiki for practical code examples showing how to use ECDH in OpenSSL, how to use the low-level APIs to achieve the same, and infos about how to handle ECDH and Named Curves.