Without breaking $F$, you can't: $S'$ is a PRF with almost the same security as $F$.
Let $k_1$ and $k_2$ be uniform random keys. Let $F$ be a PRF, with advantage $$\operatorname{Adv}^{\operatorname{PRF}}_F(A) = \lvert\Pr[A(F_{k_2}) = 1] - \Pr[A(f) = 1]\rvert$$ for any distinguisher $A$, where $f$ is a uniform random function with the domain and codomain of $F$. Let $H$ be an $\varepsilon$-almost universal hash family, so that $\Pr[H_{k_1}(x) = H_{k_1}(y)] \leq \varepsilon$ for any $x \ne y$. (Without qualification, $\varepsilon = 1/|T|$ where $T$ is the codomain of $H$.)
Define $$S'_{k_1,k_2}(m) = F_{k_2}(H_{k_1}(m)).$$
Fix any PRF-distinguisher $A'$ for $S'$ making $q$ queries, and let $U$ be a uniform random function with the domain and codomain of $S'$. We will bound the advantage of $A'$ at distinguishing $S'$ in terms of the advantage of another algorithm $A$ at distinguishing $F$ and the collision probability $\varepsilon$ of $H$:
\begin{align*}
\operatorname{Adv}^{\operatorname{PRF}}_{S'}(A')
&= \lvert\Pr[A'(S'_{k_1,k_2}) = 1] - \Pr[A'(U) = 1]\rvert \\
&\leq \operatorname{Adv}^{\operatorname{PRF}}_F(A) + \binom{q}{2} \varepsilon,
\end{align*}
where $A$ is a PRF-distinguisher for $F$. As long as $\operatorname{Adv}^{\operatorname{PRF}}_F(A)$ is small and $q$ is not too large, $\operatorname{Adv}^{\operatorname{PRF}}_{S'}(A')$ is small too.
We will do this by the triangle inequality with the intermediate probability $\Pr[A'(f \circ H_{k_1}) = 1]$ that $A'$ returns 1 on a variant $f \circ H_{k_1}$ of $S'_{k_1,k_2} = F_{k_2} \circ H_{k_1}$, where a uniform random $f$ has been substituted for $F_{k_2}$.
Define the PRF-distinguisher $A$ for $F$ by $A(\mathcal O) = A'(\mathcal O \circ H_{k_1})$. Then
\begin{align*}
\operatorname{Adv}^{\operatorname{PRF}}_F(A)
&= \lvert\Pr[A(F_{k_2}) = 1] - \Pr[A(f) = 1]\rvert \\
&= \lvert\Pr[A'(F_{k_2} \circ H_{k_1}) = 1]
- \Pr[A'(f \circ H_{k_1}) = 1]\rvert.
\end{align*}
If $A'$ is a good distinguisher for $S'$, we will find that $A$ is a good distinguisher for $F$, unless $A'$ just got lucky finding collisions in $H$.
Now consider the $q$ queries $x_1, x_2, \ldots, x_q$ submitted by $A'$ for the oracle $f \circ H_{k_1}$.
From queries to $H_{k_1}$ alone, of which we assume only the weak property of collision probabilities on two distinct inputs, an adversary could find a collision among three inputs with high probability—e.g., in a polynomial evaluation MAC $M_{r,s}(m) = s + \sum_{i=1}^{|m|} m_i r^{|m| - i + 1}$ the adversary could trivially recover the keys $r$ and $s$ from two distinct queries and find arbitrarily many collisions with probability 1 after that.
But since $f$ is a uniform random function, the only information $A'$ can learn from oracle access to $f \circ H_{k_1}$ is whether the queries collide in one of $H_{k_1}$ or $f$, or definitely do not collide in either. The adversary can adaptively act on the information that queries might collide only if a collision actually occurs in $H_{k_1}$, which happens with probability at most $\varepsilon$ for any pair of inputs submitted. Thus, to study $\Pr[A'(f \circ H_{k_1}) = 1]$, it suffices to set a bound on the probability that there is a collision at all.
Among the queries $x_1, x_2, \ldots, x_q$ submitted by $A'$ to $f \circ H_{k_1}$, the event $C$ of a collision in $H_{k_1}$ has probability
\begin{multline*}
\Pr[C] = \Pr[\exists i < j\colon H_{k_1}(x_i) = H_{k_1}(x_j)] \\
\leq \sum_{i<j} \Pr[H_{k_1}(x_i) = H_{k_1}(x_j)]
\leq \sum_{i<j} \varepsilon = \binom{q}{2} \varepsilon,
\end{multline*}
In the event $\lnot C$ that the queries do not collide in $H_{k_1}$, the distribution of each $f(H_{k_1}(x_i))$ is independent uniform random, identical to the distribution of $U(x_i)$. Hence necessarily $\Pr[A'(f \circ H_{k_1}) = 1 \mid \lnot C] = \Pr[A'(U) = 1]$, so that
\begin{align*}
\Pr[A'(f \circ H_{k_1}) = 1]
&= \Pr[A'(f \circ H_{k_1}) = 1 \mid C]\,\Pr[C] \\
&\quad + \Pr[A'(f \circ H_{k_1}) = 1 \mid \lnot C]\,\Pr[\lnot C] \\
&\leq \Pr[C] + \Pr[A'(f \circ H_{k_1}) = 1 \mid \lnot C] \\
&\leq \binom{q}{2} \varepsilon + \Pr[A'(U) = 1],
\end{align*}
and thus $\Pr[A'(f \circ H_{k_1}) = 1] - \Pr[A'(U) = 1] \leq \binom{q}{2} \varepsilon$.
Summing up,
\begin{align*}
\operatorname{Adv}^{\operatorname{PRF}}_{S'}(A')
&= \lvert\Pr[A'(S'_{k_1,k_2}) = 1] - \Pr[A'(U) = 1]\rvert \\
&\leq \lvert\Pr[A'(F_{k_2} \circ H_{k_1}) = 1]
- \Pr[A'(f \circ H_{k_1}) = 1]\rvert \\
&\quad + \lvert\Pr[A'(f \circ H_{k_1}) = 1] - \Pr[A'(U) = 1]\rvert \\
&\leq \operatorname{Adv}^{\operatorname{PRF}}_F(A)
+ \binom{q}{2} \varepsilon,
\end{align*}
QED.
This follows the structure of the proof of Lemma 3.3 in:
Shay Gueron and Yehuda Lindell, ‘GCM-SIV: Full Nonce Misuse-Resistant Authenticated Encryption at Under One Cycle per Byte’, in Proceedings of the ACM SIGSAC Conference on Computer and Communications Security, CCS 2015, pp. 109–119
Variants of the theorem appear in many earlier papers, including the MDx-MAC paper that preceded the creation of HMAC, and the HMAC/NMAC security papers.