entropy is the measure of surprise
That's informal, short and non-quantitative, but correct within that. In the case of a Random Number Generator, we must make that: entropy is the measure of surprise in the outputs of the RNG, for one skilled person (with arbitrarily large computing power) knowing the RNG design including any parameter (for MT: the Mersenne prime used, and a few others). That's for unknown seed (if any) assumed uniformly random but arbitrarily large computing power of the skilled person (unless otherwise stated).
The entropy considered here is a property of the generator, not that of one particular bitstring that it outputs.
Entropy further can be defined for the total output of a generator, or per output bit. In cryptography we measure the entropy in bit, so that it is 1 bit per output bit for an ideal uniform True RNG.
For any Pseudo RNG, the whole output is predictable from design, parameters and seed, hence the entropy in the whole output is limited to the entropy in what generates its seed, which is finite. And the entropy per output bit decreases to zero as the output size increase towards infinity.
the Mersenne Twister(MT) has high entropy.
No, because it is a PRNG (see above).
the MT is also predictable.
Yes, with enough output, and little computing power.
What's the relationship between entropy and predictability?
If a bitstring generator has the property that it's full output is predictable from a finite length prefix (as is the case for MT), then this generator has finite total entropy (bounded by said finite length in bits for Shannon entropy in bits), and vanishingly small entropy per output bit.
The converse is false for practical definition of (un)predictable. In particular, there exist practical Cryptographically Secure PRNGs (thus of finite total entropy) that are practically unpredictable.
To make things quantitative: consider a generator $G$ of arbitrarily long bitstrings. Note $G_b$ that generator restricted to its first $b$ bits. $G_b$ is susceptible to generate $2^b$ different $b$-bit bitstrings $B$ with respective probability $p_B$ (possibly $0$ for some $B$), with $1=\sum p_B$ (the sum being over $2^b$ terms $B$). $G_b$ has Shannon entropy in bits
$$H(G_b)=\sum_{B\text{ with }p_B\ne0}p_B\,\log_2\left(\frac1{p_B}\right)$$
and its average entropy per bit is $H(G_b)/b$.
For an ideal TRNG (which output is uniformly random independent bits), and any $b$, all $b$-bit bitstrings are equiprobable with $p_B=2^{-b}$ and it comes $H(G_b)=b$.
For any PRNGs with $s$-bit seed (per any distribution), $H(G_b)\le \max(b,s)$. The entropy of the generator's whole output is $H(G)=\displaystyle\lim_{b\to\infty}H(G_b)$. That is maximal with $H(G)=s$ when all seeds generate different outputs and the seed is uniformly random.